Hydrosilylation of aldehydes and ketones catalyzed by hydrido iron complexes bearing imine ligands.
نویسندگان
چکیده
Two new hydrido iron complexes (2 and 4) were synthesized by the reactions of (4-methoxyphenyl)phenylketimine ((4-MeOPh)PhC=NH) with Fe(PMe3)4 or FeMe2(PMe3)4. The molecular structures of complexes 2 and 4 were confirmed by X-ray single crystal diffraction. Using hydrido iron complexes (1-4) as catalysts, the hydrosilylations of aldehydes and ketones were investigated. The four complexes were effective catalysts for this reduction reaction. Complex 1 among them is the best catalyst.
منابع مشابه
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ورودعنوان ژورنال:
- Dalton transactions
دوره 43 30 شماره
صفحات -
تاریخ انتشار 2014